Effect of work hardening on stress corrosion cracking. Stress corrosion cracking scc of duplex stainless steel. Structural failure due to scc can be very unpredictablefailure could occur after as little as a few hours of exposure, or the equipment could continue to function normally for. Scc is a form of corrosion that occurs in nearly all alloys, including the grades of stainless steel commonly used in brewery equipment types 304, 304l, 316, and 316l.
Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Emerging issues and fundamental processes in environmental. Threshold stress intensity factor for stress corrosion cracking kiscc of az91d magnesium alloy in a simulated physiological environment has been. Stresscorrosion cracking materials performance and evaluation. Laboratory tests were conducted to investigate the stress corrosion cracking scc of 304l stainless steel used to construct the containment vessels. Schematic view of stress corrosion cracking scc and corrosion fatigue cracking. The stress intensity factor, is used in fracture mechanics to predict the stress state stress intensity near the tip of a crack or notch caused by a remote load or residual stresses. Validity of a new fracture mechanics technique for the. Smallamplitude cyclic loading, well below that needed to produce fatigue crack growth, superimposed on sustained tensile loading was observed to significantly lower the apparent threshold for stress corrosion cracking in certain instances 7, 8. Austenitic stainless steels suffer from stress corrosion cracking in hot solutions. Stress corrosion crack an overview sciencedirect topics.
Sreekumar, stress corrosion cracking of stainless steel bellows of satellite launch vehicle propellant tank assembly, eng. Evaluation of stress corrosion cracking and corrosion fatigue crack growth characteristics for martensitic stainless steel. Alloyenvironment combinations exhibiting stress corrosion cracking. Resolving one of the more serious issues, that of stress corrosion cracking, can often be achieved in a straightforward manner by accurately identifying the causes.
Environmental and material factors influence the value of threshold stress intensity. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. Stress corrosion cracking of sensitized stainless steel in simulated boiling water reactor environments is strongly affected by water chemistry such as dissolved oxygen or electrochemical potential, and concentration of impurities 4, 5. The crack starts to grow when the stress concentration at the end of the crack ki exceeds the threshold stress intensity factor for stress corrosion cracking kiscc. It predicts stress intensity near the tip of a crack caused by a remote load or residual stresses. Improvement of the threshold stress intensity factor for. Transgranular stress corrosion cracking tgscc is a typical fracture mode for the scc system of stainless steels in chloride environments, characterized by riverlike fractographs 15. Stress corrosion cracking scc is a progressive fracturing that occurs in metals as a result of the combined influence of tensile stress and a corrosive environment. In austenitic stainless steel, for example, warm chloride solutions in the presence of residual tensile stress can lead to cracking.
Ammonium hydroxide stainless steela ahow good resistance to all concentrations of ammonia. Determination of the threshold stress intensity for stress corrosion cracking k iscc of narrow areas such as weld and heataffected zone haz of a. Research program on stress corrosion cracking of stainless steel canister for concrete cask, central research institute of sdentific power industry criepi, japan, january 16, 2007. Discontinuous surface cracks during stress corrosion cracking of stainless steel single crystal l.
Nihon kikai gakkai ronbunshu, a hentransactions of the japan society of mechanical engineers, part a. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Scc is highly chemically specific in that certain alloys are likel. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. The crack tip stress intensity factor in the opening mode, ki, represents the. Determination of threshold stress intensity for chloride. Stress corrosion cracking scc studies in stainless steels and nickel alloys reveal that all grades and conditions are susceptible to scc in hightemperature water, whether deaerated or aerated, high h 2 or low, theoretical purity water or bufferedcontaminated, lower temperature or higher. Pdf stress corrosion cracking of austenitic stainless. The threshold for scc, kiscc, is the stress intensity factor above which occurs the first measurable crack extension. Effects of yield strength, corrosion potential, composition. Induced stress corrosion cracking of austenitic stainless. Stage 1 behavior in a stress corrosion study of type 304. Jan 22, 20 pure and normally very active metal is exposed and will be attacked by corrosion. This paper discusses a new approach to determination of threshold stress intensity factor for stress corrosion cracking kiscc of stainless steel in 42% mgcl2 environment at 154 c.
Tensile overload was applied to a wedge opening loaded specimen of sus316, and scc tests were carried out to determine the resultant k iscc. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Stage i exhibits a threshold ksub iscc followed by a rapid increase in crack. Stress corrosion cracking and component failure table 1. Stress corrosion cracking of austenitic stainless steels 689 ld. Typically, three regions of crackpropagation rate versus stressintensity level are found during crackpropagation experiments.
Controlling stress corrosion cracking scc in order for scc to occur, we require a susceptible material, an environment that will cause cracking of that material and a high enough stress or stress intensity factor. Because the main pipeline of the primary circuit of a nuclear power plant carries high temperature, high pressure, high flow rate, and an aqueous medium containing radioactive substances 2, under such a complicated working environment 3, austenitic stainless steel will undergo stress corrosion cracking scc 1. Threshold stress intensity factor for stress corrosion cracking kiscc of. Kiscc of solutionannealed and sensitized aisi 304 stainless steel in chloride environment has been determined using circumferential notch tensile cnt technique. From this data, stress intensity factors were calculated as 40. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors.
Steam turbines are used across the world as a source of power for many different industries. Scc occurs when the tensile stress and a specific environment are able to cause failure by their combined action, but are insufficient to cause failure by either one acting alone. Chloride stress corrosion cracking in austenitic stainless steel. At stress values below the threshold stress intensity, cracks do not propagate. Evaluation of stress corrosion cracking and corrosion fatigue. On the stress corrosion cracking mechanisms of austenitic. Therefore, a new test method for evaluating defects by ciscc using the developed tester is suggested based on the experimental results. It has been reported that the environmentalfracture is discontinuous. Corrosion pits are common sites for the initiation of stress corrosion cracks the cracks in the hinckley point disc initiated at a corrosion pit. The important general point is that those environments that cause stress corrosion are frequently highly specific to the particular. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. Effects of water chemistry and loading conditions on.
Nihon kikai gakkai ronbunshu, a hentransactions of the japan society of mechanical engineers, part. Factors affecting stress corrosion cracking scc and. Corrosion product films cpfs, such as a passive film, an oxide film or a dealloyed layer, usually form on the surfaces of a specimen andor at the crack tip during scc. Tensile overload was applied to a wedge opening loaded. Discontinuous surface cracks during stress corrosion. Stress corrosion cracking national physical laboratory. Mechanisms of stresscorrosion cracking asm international. The interaction of corrosion fatigue and stresscorrosion. Crack propagation of carbon steel cs caused by hydrogen in an overprotective buffer solution environment was investigated to determine the threshold stress intensity factor k ih for hydrogen assisted cracking hac using a wedge openload wol specimen. Prediction model for atmospheric stress corrosion cracking. To a first approximation a pit can be treated as a crack with the same crosssection, and a fracture if our crack detection system can guarantee to find any crack.
It is a theoretical construct usually applied to a homogeneous, linear elastic material and is useful for providing a failure criterion for brittle materials, and is a critical technique in the discipline of. Prevention of stress corrosion cracking of sus304 by tensile. The crack propagation velocity jumps suddenly when stresses exceed the threshold stress intensity. In essence, tests for stress corrosion cracking simply require the exposure of the. Thus, the addition of caustic soda to boiler feed waters to reduce the corrosiveness of the latter towards mild steel can result in the form of stress corrosion frequently referred to as caustic cracking. Stress corrosion cracking of facecenteredcubic alloys. This factor makes it common for scc to go undetected prior to failure. Development of chloride induced stress corrosion cracking. Threshold stress intensity for stress corrosion cracking. The critical value of stress intensity factor in mode i loading measured under plane strain conditions is known as the plane strain fracture toughness, denoted. Jan 10, 2011 the effects of overload on the threshold stress intensity factor k iscc for stress corrosion cracks scc in stainless steel were studied. When attempting to analyze the effects of corrosion fatigue on crack growth in a particular environment, both corrosion type and fatigue load levels affect crack growth in varying degrees. In this paper, a chlorideinduced stress corrosion cracking ciscc test method for spent nuclearfuelstorage canisters is presented. The fractography of transgranular stress corrosion cracking tscc of annealed 316 stainless steel s.
Effect of hydrogen content on threshold stress intensity. Anodic dissolution abstract twodimensional and threedimensional crack morphologies of stress corrosion cracking scc were studied by serialsectioning and synchrotronbased xray computed tomography. As a result, the value of k iscc was found to increase with increasing stress intensity factor. Feb 22, 2001 chloride induced cracking of stainless steels, caustic cracking of plain carbon steels, and ammonia damage to copper alloys are typical examples of this problem. Stress corrosion cracking in a brewery paul mueller company. For example, chloride stress corrosion cracking of austenitic stainless steel. Corrosion product filminduced stress facilitates stress. Stress corrosion cracking of stainless steels and nickel. Determination of threshold stress intensity factor for. Crystallographic aspects and the influence of the stress intensity factor. The typical curve has three stages, although region 3 is not always observed. Stress corrosion cracking wikimili, the best wikipedia reader. At each crack tip, the combined action of the tensile stress and specific ions in the corrosive media cause continual crack propagation with little evidence of local deformation.
Prevention of stress corrosion cracking of sus304 by. These growth rates show a continuum response across stainless steels and nickel alloys, corrosion potential and changes in dissolved o 2 and h 2, water chemistry, cold work and yield strength, temperature, stress intensity factor, irradiation, and so on, with no evidence of true thresholds or immunity. The drip procedure from the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to nuclear regulatory commission. The influence of the stress intensity factor on the. Little effect of gradeheat of stainless steel, martensite content, or h 2 fugacitypermeation rate was observed, while large effects were observed for yield strength cold work, stress intensity factor, corrosion potential, and temperature. Even with the best maintenance procedures and preventative maintenance techniques, problems can still arise. Influence of sensitization on crack growth rate of aisi 304 stainless steel as a. Standard test method for determining threshold stress. Specimen fracture occurs when the stress intensity factor range is equal to the applicable threshold stress intensity factor for stress corrosion cracking. There are, consequently, a number of approaches that we can use to prevent scc, or at least to give an acceptable lifetime. Effects of fluoride and other halogen ions on the external. Comparison of fracture mechanics and nominal stress.
Prediction model for atmospheric stress corrosion cracking of. Stress corrosion cracking of stainless steel used in drill. In materials science, fracture toughness is the critical stress intensity factor of a sharp crack where propagation of the crack suddenly becomes rapid and unlimited. The stress intensity factor k is used in the field of fracture mechanics. Fracture toughness is a quantitative way of expressing a. Lic a department of materials physics, corrosion and protection center, key laboratory for environmental fracture moe, university of science and technology. The mechanism of scc is shown as a simple representation in figure 1. Stress corrosion crack growth rates in unsensitized stainless steels and nickel. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. As its name suggests, scc takes the form of a network of cracks that eventually will lead to sudden, catastrophic failure in your tanks. Crack branching and intergranular stress corrosion cracking along random grain boundaries were observed by electronback scattering diffraction. Moreover, the cefm, which was originally developed to describe intergranular stress corrosion cracking in sensitized stainless steels is equally applicable for describing the stress corrosion cracking in lightly sensitized aluminum alloys and alloy 22.
Corrosionpedia what is the stress intensity factor k. Oct 28, 2002 this comprehensive study covers all types of corrosion of austenitic stainless steel. Life prediction for stress corrosion behavior of 316l. Stress corrosion cracking test selection corrosion doctors. Discontinuous surface cracks during stress corrosion cracking. It predicts stress intensity near the tip of a crack caused by a remote load or. Etchpitting and stereographic observations were employed in order to determine the cracking crystallography. The threshold stress intensity factor for stress corrosion cracking kiscc of the simulated heat affected zone haz of mild steel in caustic solution has been determined using circumferential.
Corrosionpedia what is stress corrosion cracking scc. Stress corrosion cracking wikimili, the best wikipedia. The kvalue decreasingtype testing method was adopted as the experimental method. Stress corrosion cracking of highstrength steels uq espace. Stress corrosion cracking scc is a fracture process that involves the combined and simultaneous action of a tensile stress and a corrosive environment. In this chapter, the conditions for the occurrence of scc are first introduced. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. It also covers methods for detecting corrosion and investigating corrosion related failure, together with guidelines for improving corrosion protection of steels.
The effects of overload on the threshold stress intensity factor k iscc for stress corrosion cracks scc in stainless steel were studied. Nureger7030, atmospheric stress corrosion cracking susceptibility of welded and unwelded 304. Smallamplitude cyclic loading, well below that needed to produce fatigue crack growth, superimposed on sustained tensile loading was observed to significantly lower the apparent threshold for stress corrosion cracking in certain. Grow rate will be a combination of corrosion and cracking. The threshold stress intensity factor stands for stress intensity above which stress corrosion cracks will initiate under plane strain conditions 9. The developed tester is easy to use with a standard compacttension ct specimen and the load is applied by a constant displacement. Stress corrosion cracking industrial metallurgists. The effects of overload on the threshold stress intensity factor kiscc for stress corrosion cracks scc in stainless steel were studied. Evaluation of stress corrosion cracking and corrosion.
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